Ooh ooh I just remembered one of my favorite ones that showed Rhodey and Tony being hilarious besties together...it's a sequel to one but I guess it can also be read as a standalone too...and it's Steve/Tony...and I guess none of that matters to me because my favorite parts are where Tony hangs out with Rhodey and Rhodey laughs at him. (And Tony fixing microwaves and the results thereof...that is also my favorite.) So!
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http://archiveofourown.org/works/351786
ETA: Just noticed that peachpai recced this above too lol.